Structures and properties of two new Lindqvist type oxidovanadium clusters functionalized by tris ( hydroxymethyl ) aminomethane
YANG Yan
TIAN Aixiang
Abstract：In this paper, through using hydrothermal technique we utilized tris (hydroxymethyl )aminometh－ane ( Tris) as organic ligands and synthesized two Lindqvist －type [ V6 O19 ]5－based compounds [ Co ( Tris)3 (H2 O)3 ( H3 V6 O19 )]· H2 O (1) and [ Zn ( Tris)3 ( H2 O)3 ( H3 V6 O19 )]· H2 O (2).Their crystal structures have been determined by single －crystal X－ray diffraction analysis.Compounds 1 and 2 are isostructural, con－taining a mix－capped Lindqvist －type [ V6 O19 ]5－anion.One octahedron coordinative Co／Zn atom links with three bridging O atoms of anion , forming the"inorganic cap".Furthermore, three Tris organic ligands offer their nine O atoms to build [V6 O19 ]5－anion.Namely, between the 19 O atoms in [V6 O19 ]5 －, 9 O atoms come from three Tris ligands.These three Tris molecules become the "organic cap"of the anion, realizing the organic func－tionalization of [V6 O19 ]5－.Additionally, we also studied the electrochemical , and photocatalytic properties of the title compounds.
Keywords：Lindqvist－type POMsTris ligandphotochemical catalysiselectrocatalystic activities
Publication Date：2019-01-01
Online Publishing Date：2025-08-15(First online date of this platform, not the publication date of the document)
Pages：8( 32-39 )