A new Anderson－based supramolecular compound constructed from inorganic polyoxometalate chains and metal －organic chains
YING Jun
ZHANG Baoyue
XIE Jishu
TIAN Aixiang
Abstract：A novel supramolecular compound based on Anderson type polyoxomatelate ,{CuII ( btx ) Na2 (H2 O)8〔H2 Cr( OH)6 Mo6 O18〕}· 〔Cr( OH)6 Mo6 O18〕· 16H2 O (1) was synthesized by hydrothermal method using a flexible bis(triazole) organic ligand 1,6－bis(1,2,4－triazole－1－y1)hexane (btx).The structure of 1 was characterized by IR , element analysis and single crystal X －ray diffraction.Compound 1 consists of two struc－tural subunits: the one－dimensional POM chain of Anderson anions linked by Na (H2 O)6+fragments and the met－al－organic chain of ligands btx linked by Cu 2+ions.The POM inorganic chains and the metal －organic chains are interconnected to form a two －dimensional lattice structure.The dissociative Anderson polyanions connect adjacent two－dimensional grid layers to form a three －dimensional supramolecular framework through hydrogen bonding forces.Photocatalytic and electrochemical properties of compound 1 were also investigated.1－CPE can be used as a potassium nitrite amperometric sensor.
Keywords：Anderson－type POMhydrothermal techniquephotochemical catalysiselectrocatalystic ac－tivitiesamperometric sensor
Publication Date：2019-01-01
Online Publishing Date：2025-08-15(First online date of this platform, not the publication date of the document)
Pages：8( 19-26 )