Hydrothermal preparation of Cu (Ⅱ) complexes prepared by novel nitrogen-containing rigid ligands
YING Jun
FU Yu-bo
TIAN Ai-xiang
Abstract：Under hydrothermal conditions, two novel rigid nitrogen-containing heterocyclic ligands are used, L1: 3-thiophene-5-difluoromethyl-2,3-Dihydro-1-H pyrazole, L2: 5-phenyl-1-H-tetrazole, Compound 1: Cu(L1)2·2H2O;Compound 2:Cu(L2)2·H2O.And the compounds were characterized by single crystal X-ray diffraction, elemental analysis and IR spectra.The results show that the all two Compounds crystallize in space group P 21/ n.Compound 1;a ((A))=5.027(5),b ((A))=31.332(5),c ((A))=6.309(5), β(°)=106.866(5),V ((A)3)=951.0(12),Z=2, R1=0.0635, R2=0.1768,GOF=0.972.Compound 2;a ((A))=16.570(5),b ((A))=6.965(5),c ((A))=17.753(5), β(°)=92.221(5), V ((A)3)=2047.3(17),Z=4,R1=0.0458,R2=0.1134,GOF=0.977.
Keywords：complexhydrothermal methodstructural characterization
Publication Date：2017-01-01
Online Publishing Date：2025-08-15(First online date of this platform, not the publication date of the document)
Pages：6( 161-166 )