A metal-organic complex based triangular ligand transformation in situ and Zn(II): synthesis, structure and photoluminescence property
WANG Xiang
YU Xiao-wen
LIN Lin
LIU Jia-huan
Abstract：A metal-organic complex based on 3,5-di-[1,2,4]triazol-1-yl-benzoic acid (HDTBA) and Zn(II), [Zn(DTBA)Cl] (1), has been synthesized under hydrothermal condition, which is characterized by single crystal X-ray diffraction and IR spectra.The ligand DTBA is prepared by the transformation in situ of 3,5-di-[1,2,4]triazol-1-yl-benzonitrile (DTCN).Compound 1 has a 2D layer structure, in which two DTBA are bridged through two Zn(II) atoms to give a binuclear circle building unit {Zn/DTBA}2.These building units {Zn/DTBA}2 are linked each other in a perpendicular mode to form a 2D (4,4)-connected network.The photoluminescence property of compound 1 has also been studied.
Keywords：metal-organic complextransformation in situphotoluminescence property
Publication Date：2017-01-01
Online Publishing Date：2025-08-15(First online date of this platform, not the publication date of the document)
Pages：5( 151-155 )