Hydrothermal synthesis, crystal structure and fluorescent a new supramolecular compound （H2 bbi）5 （HP2 Mo5 O23 ） （H2O）2
Abstract：A dimensional supramolecular hybrid, （ HE bbi ） 5 （ HP2 Mo5 023 ） 2 （ H2 O） 2 （ bbi = 1,1＇- （ 1,4 - butanediyl） bis （imidazole）, has been synthesized by mild hydrothermal reaction and structurally characterized by elemental analyses, IR, and single - crystal X - ray diffraction analysis. The compound is crystallized in the monoclinic, space groupP2（1）/c, a = 17. 253（5）A, b = 21. 169（5） A, c = 25. 397（5） A, g = 4,β = 104. 537（5） A,V = 8979（4）A^3,R1 = O. 0383, wR2 = 0. 0868. The crystal structure shows that two crystallo- graphic independent Standberg -type[ HPEMo5 02323 ] s- anions and five protonated H2bbi ligands are interlinked into one dimensional chain by hydrogen bonding interactions, Moreover, the title compound exhibits blue emis- sion in the solid state at room temperature.
Keywords：supramolecular compoundhydrothermal synthesiscrystal structurefluorescence property
Publication Date：2012-01-01
Online Publishing Date：2025-08-15(First online date of this platform, not the publication date of the document)
Pages：6( 139-144 )