Electrical conductivity property of binary systems composed of N-butyl-3-methyl pyridinium bis(trifluoromethylsulfonyl) imide and alcohols solvents
Abstract:A novel hydrophobic ionic liquid N-butyl-3-methyl pyridinium bis(trifluoromethylsulfonyl)imide([C4M3Py][NTf2]) is synthesized and characterized.The electrical conductivities of three binary sys-tems composed of the ionic liquid and methanol,ethanol,and isopropanol are determined respectively.The re-sults show the electrical conductivities of the binary systems are greater than that of the pure ionic liquid and thestrength sequence of the conductivities is: k([C4M3Py][NTf2]+ methanol) k([C4M3Py][NTf2 + etha-nol) k([C4M3Py][NTf2 + isopropanol).The relationship between the ionic liquid concentrations and theconductivities of the mixed systems is described by an empirical Castell-Amisequation.
Keywords:Bis(trifluoromethylsulfonyl) imideionic liquidelectrical conductivitymixed system
Publication Date:2012-01-01
Online Publishing Date:2025-08-15(First online date of this platform, not the publication date of the document)
Pages:6( 41-46 )
