DOI: 10.12187/2024.05.014
Study on the differences of pyrolysis products of domestic and foreign cigar tobaccos
ZHANG Cunyong
ZHUANG Haifeng
SHI Yaqi
ZOU Peng
DING Naihong
ZONG Kun
JIA Liangyuan
GUO Dongfeng
Abstract:A U-shaped fixed bed reaction system was used to conduct pyrolysis experiments on 35 types of cigar to-baccos from eight different regions at home and abroad.The produced volatiles were analayzed in real-time by photoionization mass spectrometry(PI-MS).The principal component analysis(PCA)method was used to statistically analyze the obtained MS datas.The results showed that a total of 74 shared pyrolysis products were identified in the 35 types of cigar tobaccos,mainly hydrocarbons,phenols,ketones,alcohols,esters,and nitrogen-containing substances.There were significant differences in the composition of pyrolysis products between domestic and foreign cigar tobaccos.Especially,the domestic cigar coats had a much higher content of nicotine than the foreign cigar coats,whereas the relative content of fragrant components such as methylcyclopentenone,2,3-dimethyl-2-cyclopentenone,and 2,5-dimethylcyclopentenone in the pyrolysis products of domestic cigar coats was lower than that of foreign cigar coats.The relative content of fragrant components such as 3-methylpyridine,2,5-dimethylcyclopentenone,and(+)-limonene in the pyrolysis products of domestic cigar chips was lower than that of foreign cigar chips.In addition,the characteristic pyrolysis products of cigar tobaccos screened by PCA were con-sistent with the results of routine chemical composition analysis of cigar tobaccos,confirming the accuracy of the experimental analysis results.
Keywords:cigar tobaccospyrolysis productsphotoionization mass spectrometryonline analysisprincipal component analysis
Publication Date:2024-10-15
Online Publishing Date:2025-08-15(First online date of this platform, not the publication date of the document)
Pages:9( 118-126 )
