Research progress of hydrdysis reaction of nitriles to form amide derivatives catalyzed by metal catalyst
XU Fen
KANG Wei-fen
MENG Yan-yu
ZHANG Li-chao
FANG Shao-ming
Abstract:Considering the high atom economy and selectivity towards hydrolysis reaction derivatives of nitriles to form amides,progress in recent years for this transformation catalyzed by different metal catalysts was reviewed such as a variety of catalysts composed of transition-metal complexes such as Mo,Ru,Rh,Pd and Au/Ag.Specially,Ru-metal catalysts was exploited deeply and draw more attention of science researcher. However,hydrolysis reaction derivatives of nitriles to form amides catalyzed by metal catalysts remains a formi-dable challenge,including the development of heterogeneous Ru-metal catalysts and high selectivity catalysts, bringing insight into the mechanism of homogeneous and heterogeneous catalytic reaction,seeking for new sys-tem with pure water as solvent.
Keywords:metal catalysthydrdy-sis reaction of nitrilesamide derivative
Publication Date:2017-01-01
Online Publishing Date:2025-08-15(First online date of this platform, not the publication date of the document)
Pages:10( 72-81 )

ISSN:2096-1553
Year, Vol.(Issue):2017,32(1)