Dynamic parameters of low temperature oxidation of weakly viscous coal at different gas concentration conditions
WANG Fei
JING Changbao
YU Bo
LIU Hongliang
ZHANG Baodi
WANG Zhenping
Abstract:In order to study the characteristics of low-temperature oxidation of weakly viscous coal under different gas concentration conditions inside the mining area and the change law of kinetic parameters,this paper adopts the coal spontaneous combustion tem-perature programming experimental system to test and analyze the change law of gaseous products with temperature during the low-temperature oxidation of weakly viscous coal under different gas concentration conditions,and calculate the limit parameters and ac-tivation energy during the low-temperature oxidation of weakly viscous coal.The results show that:CO gas can be used as the main predictor gas for spontaneous combustion prevention and control of weakly viscous coal,and C2H4 gas and R2 can be used as auxili-ary indicators for predicting the degree of spontaneous combustion of weakly viscous coal;the maximum limit parameters of meth-ane samples with different gas concentration conditions are distributed in the temperature range of 60-85℃,which is similar to the critical temperature of spontaneous combustion of coal.With the methane volume fraction increasing from 0 to 4%,the apparent ac-tivation energy of weak sticky coal shows a gradual increasing trend,increasing by 35.061,18.426 and 25.837 kJ/mol,respectively.
Keywords:coal spontaneous combustiongas concentrationtemperature programminglow temperature oxidationactivation en-ergy
Publication Date:2023-12-20
Online Publishing Date:2025-08-15(First online date of this platform, not the publication date of the document)
Pages:9( 64-72 )
