Synthesis and Crystal Structures of Triorganotin with 1,4-Cyclohexanedicarboxylic Acid
Abstract：Four new compounds[(Ph3Sn)2](C8H10)(COO)2] 1,(Me3Sn)2[(C8H10)(COO)2] 2,[(n - Bu)3 Sn]2 [(C8 H10) (COO)2 ] 3 和 [ (PhCH2)3 Sn]2 [(C8 H10 ) (COO)2 ] 4 have been synthesized by the reaction of trans-1, 4-Cyclohexane dicarboxylic acid and triphenyltin, trimethyltin, tributyltin, tribenzyltin. All the compounds have been characterized by element analyses, IR spectra, 1H NMR spectra. The compound 1 is also characterized by X-ray diffraction crystallography. The data indicated that compound 1 is a dinuclear monomer, both of the carboxyl derived from the trans-1,4-Cyclohexanedicarboxylic acid coordinating to the tin atoms. The coordination geometry about the Sn atoms are distorted trigonal bipyramidal geometry.
Keywords：trans-14-CyclohexanedicarboxylicX-ray diffractionsynthesizestructure characterization
Publication Date：2012-01-01
Online Publishing Date：2026-08-28(First online date of this platform, not the publication date of the document)
Pages：4( 58-61 )