Synthesis and characterization of dibutyltin (Ⅳ) o-vanillin-2-thiophenoylhydrazone
Abstract:A new dibutyltin(IV) complex with Schiff base of o-vanillin-2-thiophenoylhydrazone [(n-C4H9)2Sn[(C13H10N2O3S)]2 was synthesized by the reaction of (C4H9)2SnCl2 with o-vanillin-2-thiophenoylhydrazone.Complex has been characterized by elemental,IR,1H NMR analyses and X-ray crystallographic diffraction analyses.The tin atom exhibits a distorted trigonal bipyramid coordination geometry.Two molecules form a weak-bridged dimmer with weak interactions of Sn…O.
Keywords:o-vanillin-2-thiophenoylhydrazonedibutyltinweak-bridged dimmer
Publication Date:2008-01-01
Online Publishing Date:2026-08-28(First online date of this platform, not the publication date of the document)
Pages:3( 14-16 )