Synthesis and Crystal Structures of the Diphenyltin (Ⅳ) Salicylaldehyde Thiophene-2-Carboxylic Hydrazone
YIN Han-dong
LI Feng
ZHOU Ya-dong
Abstract:A new diphenyltin (Ⅳ) compound with Schiff base of salicylaldehyde thiophene-2-carboxylic hydrazone Ph2Sn (C12 H8N2O2S ) was synthesized by the reaction of PhsSnCl with salicylaldehyde thiophene-2-carboxylic hydrazone. This compound has been characterized by elemental,IR,1H NMR analyses and X-ray crystallographic diffraction analyses. The compound is a monomer in which the tin atom adopts five-coordinated in distorted trigonal-bipyramidal geometry.
Keywords:salicylaldehyde thiophene-2-carboxylic hydrazonediphenyltinsynthesiscrystal structure
Publication Date:2007-01-01
Online Publishing Date:2026-08-28(First online date of this platform, not the publication date of the document)
Pages:3( 12-14 )