Effects of Mass Ratio of Copper on Reduction of 2,4-dichlorophenol by Fe/Cu and Reduction Pathway
RUAN Xia
LIU Hong
MA Chi
FAN Xianyuan
Abstract：Aim at the problems that Fe/Ni and Fe/Pd bimetal are high cost and weak hydrophobicity,nanoscale Fe/Cu bimetal was modified and used to dechlorinate 2,4-dichlorophenol (2,4-DCP).The effects of mass ratio of copper (ω(Cu)) on the reduction of 2,4-dichlorophenol by Fe/Cu were investigated.The results showed that when the reaction time was 80 h,the removal rate of 2,4-DCP by Fe/Cu (ω(Cu)=10％) was nearly 100％ and the intermediate,4-chlorophenol (4-CP),was converted into end product,phenol (CA).The yield of CA was found to reach to 91.8％.The dechlorination pathways of 2,4-DCP were confirrned,that is,2,4-DCP was dechlorinated a chlorine atom to produce 4-CP at first,and then the dechlorination was performed sequentially to form CA.2,4-DCP was dechlorinated two chlorine atoms simultaneously to generate CA.XRD analysis indicated that Fe0 was oxidized to Fe3O4 and Fe2O3 and Cu0 was oxidized to CuO after the reaction.
Keywords：mass ratio of copperFe/Cu bimetalreduction24-dichlorophenol
Publication Date：2017-01-01
Online Publishing Date：2025-08-15(First online date of this platform, not the publication date of the document)
Pages：6( 43-48 )