Influencing factors and laws of lignite gasification in supercritical water
ZHENG Shaohua
WANG Xiaoliang
LI Mingtong
XIN li
RAN Mengjiao
CAO Dongliang
Abstract:In order to study the possibility of lignite liquefaction and gaslization in SCW ( supercritical water ) and its influencing factors, lignite liquefaction experiments were carried out under the conditions of different catalysts , temperature and particle size of coal samples.The results show that a certain amount of oil could be produced when lignite was liquefacted in the state of SCW when the temperature reached super point , the reaction of liquefaction speed up significantly , and the conversion rate goes up from 15.84%to 94.64%and output of oil was only 3.36 ml, 2.69 g.The conversion rate is 12.78%.Catalyst KOH made the conversion rate of lignite into gases or liquids reach the highest level of 94.64%.But the oil transforming rate of lignite was as low as 12.78%.When lignite particle size at 0.9~2.0 mm with catalyst K2CO3, the oil produced was 8.01ml, 6.41g, and the conversion rate was 30.48%.The bigger coal sample particle is , the smaller the conversion rate is and higher oil yield is.So un-der the state of supercritical water , the lignite particle size at 0.9~2.0 mm with catalyst K2 CO3 is the best way to convert lignite into oils.
Keywords:supercritical waterligniteliquefactionparticle sizecatalysts
Publication Date:2013-01-01
Online Publishing Date:2025-08-15(First online date of this platform, not the publication date of the document)
Pages:5( 39-43 )